Product ID:6401, 6402, 6403, 6404, 6405, SOLVENT BLEND
MSDS Date:10/14/1988
FSC:6850
NIIN:00D020284
MSDS Number: CCLMF

VALVOLINE OIL CO SUBSIDIARY OF ASHLAND OIL INC.

200 E MAIN ST
LEXINGTON, KY 40512
US

Emergency Phone: 800-ASHLAND/800-274-5263

Info Phone: 606-264-7000/7616;FAX 601-429-0537

Cage: 72527

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

METHYLENE CHLORIDE (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 40-55%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEAVY NAPHTHA SOLVENT EXTRACT

CAS: 64741-98-6

Fraction By Weight: 10-25%

O-CRESOL (SARA 302/313) (CERCLA)

CAS: 95-48-7

RTECS: GO6300000

Fraction By Weight: 1-5%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL (SARA 302/313) (CERCLA)

CAS: 108-95-2

RTECS: SJ3327000

Fraction By Weight: 1-5%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE
IRRITATION,REDNESS,TEARING,BLURRED VISION. BREATHING:MAY CAUSE
NAASAL & RESOPIRATORY IRRITATION,CNS
EFFECTS,DIZZINESS,WEAKNESS,FATIGUE,NAUSEA,HEADACHE,UNCONSCIOUSNESS,
DEATH. SWAL LOWING:MAY CAUSE G/I
IRRITATION,NAUSEA,VOMITING,DIARRHEA. ASPIRATION OF MATERIAL INTO
LUNGS MAY CAUSE (SEE SIGNS & SYMP)
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS FOUND METHYLEND CHLORIDE LISTED. SEE REPORTS
FOR DETAILS.
Effects of Overexposure:CHEMICAL PNEUMONITIS WHICH MAY BE FATAL.
SKIN:MAY CAUSE IRRITATION,BURNS. CHRONIC-IN HUMANS:LIVER
ABNORMALITIES,KIDNEY DAMAGE,EYE DAMAGE. IN ANIMALS:BIRTH DEFECTS.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS.

First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION.
EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM
EXPOSURE. A ID OR RESTORE BREATHING AS NEEDED. INGESTED:DO NOT
INDUCE VOMITING. KEEP WARM & QUIET. GET IMMEDIATE MEDICAL
ATTENTION. ASPIRATION OF MATERIAL INTO LUNGS DURING VOMITING MAY
CAUSE CHEMICAL PNEUMONITIS

Flash Point Method:TCC
Flash Point:140F,60C
Lower Limits:1.0
Extinguishing Media:ALCOHOL FOAM, WATER FOG
Fire Fighting Procedures:WATER MAY BE USED TO KEEP EXPOSED CONTAINERS
COOL. WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE
OPERATED IN POSITIVE PRESSURE MODE FOR FIGHTING FIRE
Unusual Fire/Explosion Hazard:NEVERUSE A TORCH ON OR NEAR DRUM (EVEN
EMPTY) BECAUSE IT CAN EXPLODE.

Spill Release Procedures:SMALL SPILL:ABSORB ON PAPER ETC. & TRANSFER TO
HOOD. LARGE SPILL:EVACUATE AREA. STOP SPILL & DIKE TO CONTAIN.
RECOVER LIQUID. ABSORB REMAINDER & SHOVEL INTO CONTAINERS.
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. OBSERVE WITH THEM ALL HAZARD PRECAUTIONS
LISTED IN THIS DOCUMENT.
Other Precautions:NONE

Respiratory Protection:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL
ATTENTION. EYE:FLUSH W/WATER TO 15 MIN. SKIN:WASH W/SOAP & WATER.
REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE
FROM EXPOSURE. AI D OR RESTORE BREATHING AS NEEDED. INGEST
Ventilation:USE MECHANICAL (GENERAL) VENTILATION & LOCAL EXHAUST TO
KEEP EXPOSURE Protective Gloves:RESISTANT GLOVES (NITRILE, NEOPRENE)
Eye Protection:CHEMICAL SPLASH GOGGLES. COMPLY W/OSHA
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health
NONE

HCC:F4
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:102F,39C
Vapor Pres:<1 MM
Vapor Density:>1
Spec Gravity:1.1
pH:10.25
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:YELLOW-GREENISH BROWN LIQUID EMULSION
Percent Volatiles by Volume:55-70

Stability Indicator/Materials to Avoid:YES
MFR GAVE NO INFORMATION OF MSDS.
Stability Condition to Avoid:MFR GAVE NO INFORMATION OF MSDS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROGEN CHLORIDE, PHOSGENE, VARIOUS HYDROCARBONS
Conditions to Avoid Polymerization:CANNOT OCCUR

Waste Disposal Methods:SMALL SPILL:ALLOW VOLITILES TO EVAPORATE.
DISPOSE OF REMAINDER I/A/W APPLICABLE REGULATIONS. LARGE
SPILL:DEPOSIT IN LANDFILL I/A/W FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.